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Dimethylmercury

(Redirected from Dimethyl mercury)
</table> Dimethylmercury (CH3HgCH3) is a flammable, colorless liquid, and is described as having a slightly sweet smell. It is an extremely dangerous chemical. Absorption of doses as low as 0.1 mL are fatal. Dimethylmercury can seep through rubbers and plastics. Therefore, most laboratory gloves do not provide adequate protection from this chemical.
Properties

General

Name Dimethylmercury
Chemical formula CH3HgCH3
Appearance Colorless liquid

Physical

Formula weight 230.659 amu
Melting point 230 K (-43 °C)
Boiling point 360–370 K (87–97 °C)
Density ? kg/m3
Solubility ?

Thermochemistry

ΔfH0gas ? kJ/mol
ΔfH0liquid 55–60 kJ/mol
ΔfH0solid 162.2 kJ/mol
S0gas, 1 bar ? J/mol·K
S0liquid, 1 bar ? J/mol·K
S0solid ? J/mol·K

Safety

Ingestion Fatal
Inhalation Fatal
Skin Fatal
Eyes Fatal

SI units were used where possible. Unless otherwise stated, standard conditions were used.

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Table of contents

Use

Dimethylmercury is most often used in toxicology experiments as a fixed point of reference due to its extreme toxicity. It has also been used to calibrate NMR instruments for detection of mercury.

Well known incidents involving dimethylmercury

In 1997, Dr. Karen Wetterhahn, an experienced chemist working at Dartmouth College, died after she was exposed to dimethylmercury. After her death, the Karen Wetterhahn Memorial Award was created in her honor. Its purpose is to "recognize an outstanding graduate student or post-doctoral researcher who studies metals and best demonstrates the qualities of scientific excellence exhibited by Dr. Wetterhahn". [1]

See also

External links








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