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Dimethoxyethane

(Redirected from Dimethyl glycol)


Dimethoxyethane
Chemical name1,2-Dimethoxyethane
Chemical formulaC4H10O2
Molecular mass90.12 g/mol
Melting point-58 °C
Boiling point85 °C
Density0.8683 g/cm3
CAS number110–71–4
SMILESCOCCOC

Dimethoxyethane, also known as glyme, monoglyme, dimethyl glycol, ethylene glycol dimethyl ether, dimethyl cellosolve, and DME, is a clear, colorless, and liquid ether that is used as a solvent. Dimethoxyethane is moderately soluble in water (10 g/100 ml).

Dimethoxyethane is often used as a higher boiling alternative to diethyl ether and THF. Dimethoxyethane forms chelate complexes with cations and acts as a bidentate ligand. It is therefore often used in organometallic chemistry like Grignard reactions, hydride reductions, and palladium catalyzed reactions like Suzuki reactions and Stille coupling. Dimethoxyethane is also a good solvent for oligo- and polysaccharides.

Dimethoxyethane is also used as solvent for electrolytes of lithium batteries.

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